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- W2026417312 abstract "The reaction of methyllithium with the tmeda complex of ((trimethylsilyl)benzyl)zinc chloride in the presence of 1,2-bis(dimethylamino)ethane (tmeda) in 2:1 molar ratio quantitatively yields the heteroleptic zincate [Li(tmeda)2]+[Me3-nZn{CH(SiMe3}Ph]n]- (n = 1, 1). Under similar conditions, MeLi and ((trimethylsilyl)benzyl)lithium react with bis((trimethylsilyl)benzyl)zinc to form the zincates with n = 2 (2) and 3 (3), respectively. The molecular structures of 1 and 2 show shorter Zn−C bond lengths to the methyl group than to the benzylic substituent." @default.
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- W2026417312 date "1998-03-01" @default.
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- W2026417312 title "Synthesis and Structures of Solvent-Separated Lithium Zincates of the Type [Li(tmeda)<sub>2</sub>]<sup>+</sup>[Me<sub>3</sub><sub>-</sub><i><sub>n</sub></i>Zn{CH(SiMe<sub>3</sub>)Ph}<i><sub>n</sub></i>]<sup>-</sup> (<i>n</i> = 1−3, tmeda = 1,2-Bis(dimethylamino)ethane)" @default.
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- W2026417312 doi "https://doi.org/10.1021/om971092c" @default.
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