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- W2026432010 abstract "Auf Grund der systematisierten Angaben über die Kristallstrukturen der MeSO4 · nH2O-Salztypen, wo Me = Mg2+, Ni2+, Co2+, Fe2+, Cu2+ und n = 0–7 ist, wurde festgestellt, daß die Strukturdifferenzen eines gegebenen chemischen Typs Metallsulfat-Hydrat durch die Eigenschaften des Metallions bestimmt werden. In dieser Hinsicht werden die Kristallstrukturen der verschiedenen Hydrate behandelt. Die Kristallstrukturdifferenzen der Heptahydrate sowie das Vorhandensein - oder Nichtvorhandensein von Hydraten einiger der behandelten Ionen werden durch die Elektronenkonfigurationen der besprochenen Metallionen erklärt. Die Deformationstendenz der oktaedrischen Umgebung dieser Metallionen nimmt in folgender Reihe zu: On the basis of the systematized data on the crystal structure of salts of the MeSO4 · nH2O type, where Me = Mg2+, Ni2+, Zn2+, Co2+, Fe2+, Cu2+ and n = 0–7, it is established that the differences in the structures of given chemical type metal sulphate crystal hydrates are determined by the nature of the metal ion. The differences in the crystal structure of the heptahydrate, as well as the existence or non-existence of crystal hydrates of some of the ions considered are explained with the electron configuration of the metal ions. The deformation trend of the octahedral coordination of the metal ions considered increases in the following way:" @default.
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- W2026432010 date "1977-01-01" @default.
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- W2026432010 title "Über die Kristallstrukturdifferenzen der MeSO4 · nH2O-Salztypen" @default.
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- W2026432010 doi "https://doi.org/10.1002/crat.19770120503" @default.
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