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- W2026438599 abstract "The subsolidus phase diagram of the system Y2O3-BaO-CuO at 950° C in air has been investigated. In the binary system BaO-CuO the compound Ba2CuO3+δ has been isolated and a new compound with composition in the vicinity of Ba3Cu5O8+δ has been found. In the binary system BaO-Y2O3 it is shown in that the compounds “Ba4Y2O7” and “Ba2Y2O5” are oxycarbonates with composition Ba4Y2O7·CO2 and Ba2Y2O5·2CO2. New compounds that have been identified in the ternary system Y2O3-BaO-CuO are YBa4Cu3O8.5+δ, Y3Ba8Cu5O17.5+δ and a compound with composition close to YBa5Cu Cu2O8.5+δ. The oxygen content and the oxidizing power of these compounds has been measured. The oxygen content depends on the preparation method. Lists of interplanar spacings, relative intensities and h k l indices of these oxygen deficient perovskites as determined from X-ray powder diffraction measurements are presented and possible structures of the unit cells are described. Phase equilibrium relations have been investigated and tie lines in the phase diagram are presented." @default.
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- W2026438599 date "1988-03-01" @default.
- W2026438599 modified "2023-10-14" @default.
- W2026438599 title "Compounds and phase compatibilities in the system Y2O3-BaO-CuO at 950°C" @default.
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- W2026438599 doi "https://doi.org/10.1016/0921-4534(88)90071-8" @default.
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