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- W2026454611 abstract "The departure of the rest potential of a platinum electrode in oxygen-saturated 1 M H2SO4 from the thermodynamically reversible oxygen value is discussed in terms of a mixed potential mechanism. An examination is made of the importance of metal dissolution in addition to the anodic processes generally considered to determine the rest potential, namely oxygen adsorption and impurity oxidation. It is demonstrated that oxygen adsorption is important only at short times and is insignificant at the equilibrium rest potential. Platinum has been shown to dissolve on open circuit and to account for about half of the current required to hold a smooth electrode at 1.23 V. Comparison of the properties of a smooth and a platinized electrode leads to the conclusion that metal dissolution is the major process responsible for the rest potential deviating from the reversible value on platinized platinum. For smooth platinum, impurity oxidation also plays a significant role." @default.
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- W2026454611 title "The rest potential of platinum electrodes in oxygensaturated 1 M sulphuric acid" @default.
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