Matches in SemOpenAlex for { <https://semopenalex.org/work/W2026458034> ?p ?o ?g. }
- W2026458034 endingPage "6835" @default.
- W2026458034 startingPage "6823" @default.
- W2026458034 abstract "Femtosecond time-resolved photoelectron imaging (TR-PEI) is applied to the (1 + 2‘) resonance-enhanced multiphoton ionization of pyrazine (1,4-diazabenzene) via the S1 state. The intersystem crossing (ISC) from the S1 (nπ*) to the T1 (nπ*) state and the ionization dynamics from 3s and 3pz Rydberg states are investigated. Rotational revival features, observed in the time-resolved photoelectron intensities from the T1 state populated by ISC as well as from the optically prepared S1 state, are analyzed in detail. The alignment at the rotational revival time in the T1 state is found to be much smaller than that in the S1 state. Numerical calculations, using the molecular eigenstate basis and taking account of the angular momentum coupling, to model the transfer of coherence between the S1 and T1 states are presented. The calculated time dependence of signal strength and the axis alignment are found to be in excellent agreement with the observed profiles. The diminished alignment in T1 is explained by the angular momentum coupling mechanism in ISC. Comparison is also made with the rotational coherence transfer in intramolecular vibrational redistribution (IVR). Photoelectron angular distributions (PADs) were also measured in the laboratory frame from spatially aligned ensembles in the 3s and 3pz Rydberg states. The results are qualitatively explained on the basis of the selection rules upon photoionization." @default.
- W2026458034 created "2016-06-24" @default.
- W2026458034 creator A5004124288 @default.
- W2026458034 creator A5039297625 @default.
- W2026458034 creator A5085025891 @default.
- W2026458034 date "2004-07-28" @default.
- W2026458034 modified "2023-10-17" @default.
- W2026458034 title "Femtosecond Photoelectron Imaging on Pyrazine: S<sub>1</sub> → T<sub>1</sub> Intersystem Crossing and Rotational Coherence Transfer" @default.
- W2026458034 cites W118337339 @default.
- W2026458034 cites W1616401168 @default.
- W2026458034 cites W1620624748 @default.
- W2026458034 cites W1942151687 @default.
- W2026458034 cites W1968253807 @default.
- W2026458034 cites W1974359025 @default.
- W2026458034 cites W1975377851 @default.
- W2026458034 cites W1985161599 @default.
- W2026458034 cites W1989224733 @default.
- W2026458034 cites W1989481671 @default.
- W2026458034 cites W1995069503 @default.
- W2026458034 cites W1995215468 @default.
- W2026458034 cites W2002207671 @default.
- W2026458034 cites W2005708068 @default.
- W2026458034 cites W2006558530 @default.
- W2026458034 cites W2006959485 @default.
- W2026458034 cites W2010379299 @default.
- W2026458034 cites W2012270818 @default.
- W2026458034 cites W2013488573 @default.
- W2026458034 cites W2014520751 @default.
- W2026458034 cites W2018178961 @default.
- W2026458034 cites W2020165380 @default.
- W2026458034 cites W2021814731 @default.
- W2026458034 cites W2023875023 @default.
- W2026458034 cites W2024481252 @default.
- W2026458034 cites W2026151643 @default.
- W2026458034 cites W2027746626 @default.
- W2026458034 cites W2028869526 @default.
- W2026458034 cites W2029267371 @default.
- W2026458034 cites W2033242807 @default.
- W2026458034 cites W2033784414 @default.
- W2026458034 cites W2034021130 @default.
- W2026458034 cites W2041585528 @default.
- W2026458034 cites W2054505829 @default.
- W2026458034 cites W2054557339 @default.
- W2026458034 cites W2057018908 @default.
- W2026458034 cites W2057247818 @default.
- W2026458034 cites W2065517414 @default.
- W2026458034 cites W2065819539 @default.
- W2026458034 cites W2069079535 @default.
- W2026458034 cites W2070270796 @default.
- W2026458034 cites W2079425721 @default.
- W2026458034 cites W2084002253 @default.
- W2026458034 cites W2086067841 @default.
- W2026458034 cites W2086461194 @default.
- W2026458034 cites W2087306996 @default.
- W2026458034 cites W2087878204 @default.
- W2026458034 cites W2089183273 @default.
- W2026458034 cites W2092131542 @default.
- W2026458034 cites W2099884291 @default.
- W2026458034 cites W2114316337 @default.
- W2026458034 cites W2134663739 @default.
- W2026458034 cites W2166603911 @default.
- W2026458034 cites W2170812193 @default.
- W2026458034 cites W2171748234 @default.
- W2026458034 cites W2178042910 @default.
- W2026458034 cites W2922267790 @default.
- W2026458034 cites W3114629105 @default.
- W2026458034 cites W4256313596 @default.
- W2026458034 cites W666119 @default.
- W2026458034 cites W2027116143 @default.
- W2026458034 doi "https://doi.org/10.1021/jp0484985" @default.
- W2026458034 hasPublicationYear "2004" @default.
- W2026458034 type Work @default.
- W2026458034 sameAs 2026458034 @default.
- W2026458034 citedByCount "28" @default.
- W2026458034 countsByYear W20264580342012 @default.
- W2026458034 countsByYear W20264580342013 @default.
- W2026458034 countsByYear W20264580342014 @default.
- W2026458034 countsByYear W20264580342015 @default.
- W2026458034 countsByYear W20264580342016 @default.
- W2026458034 countsByYear W20264580342017 @default.
- W2026458034 countsByYear W20264580342019 @default.
- W2026458034 countsByYear W20264580342020 @default.
- W2026458034 crossrefType "journal-article" @default.
- W2026458034 hasAuthorship W2026458034A5004124288 @default.
- W2026458034 hasAuthorship W2026458034A5039297625 @default.
- W2026458034 hasAuthorship W2026458034A5085025891 @default.
- W2026458034 hasConcept C120665830 @default.
- W2026458034 hasConcept C121332964 @default.
- W2026458034 hasConcept C145148216 @default.
- W2026458034 hasConcept C155675718 @default.
- W2026458034 hasConcept C158749347 @default.
- W2026458034 hasConcept C167735695 @default.
- W2026458034 hasConcept C167812310 @default.
- W2026458034 hasConcept C178790620 @default.
- W2026458034 hasConcept C181500209 @default.
- W2026458034 hasConcept C184779094 @default.
- W2026458034 hasConcept C185592680 @default.
- W2026458034 hasConcept C198291218 @default.