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• W2026478575 abstract "Theoretical and experimental values have been determined for the pressure broadening of the ν1 + ν3 band of acetylene by hydrogen and deuterium at 195 K, and experimental values of the pressure shifts have been determined. Theoretical values have been calculated on the basis of a recent potential energy surface using the close coupling scheme. We discuss the detailed contribution of the various rotational angular momenta of the perturbing gas and the ortho and para contribution to the total pressure broadening cross-sections. We give routes to circumvent the computational cost of such calculations. Experimental values have been measured using a tunable diode laser spectrometer assuming a Voigt line shape. These pressure broadening parameters are compared with measurements performed recently at room temperature and with present measurements performed at 195 K in the ν1 + ν3 band of acetylene. A satisfactory agreement is obtained with the present results and available ones at 295 K." @default.
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• W2026478575 date "2009-07-01" @default.
• W2026478575 modified "2023-09-27" @default.
• W2026478575 title "Experimental line broadening and line shift coefficients of the acetylene ν1+ν3 band pressurized by hydrogen and deuterium and comparison with calculations" @default.
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• W2026478575 doi "https://doi.org/10.1016/j.jms.2009.01.011" @default.
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