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- W2026486509 abstract "The D-isomer distribution of alkanes isolated following hydrous pyrolysis of Messel shale in D2O by Hoering is much more broad than that predicted by statistical, sequential D/H exchange. This result is in contrast to the D-isomer profile for deuterated alkane generated in the system through the purposeful addition of alkene, which yields a profile in agreement with calculation. Thus, the generation of the alkanes from kerogen involves precursors which can undergo simultaneous deuteration at several sites, or accumulation and linking of smaller, preexchanged units. These scenarios receive some support from Hoering's data for recovered pristane, which displayed a bimodal D-isomer distribution. In this case the distribution was very well matched by the sums of two distributions calculated on the basis of two separate H/D exchanges taking place at different sites at different rates." @default.
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- W2026486509 date "1992-01-01" @default.
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- W2026486509 title "Comments on the source of petroleum hydrocarbons in hydrous pyrolysis" @default.
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- W2026486509 doi "https://doi.org/10.1016/0146-6380(92)90145-n" @default.
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