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- W2026486548 abstract "Quasi-reversible and direct electrochemistry of cytochrome c (cyt. c) has been obtained at a novel electrochemical interface constructed by self-assembling gold nanoparticles (GNPs) onto a three-dimensional silica gel network, without polishing or any modification of the surface. A cleaned gold electrode was first immersed in a hydrolyzed sol of the precursor (3-mercaptopropyl)-trimethoxysilane to assemble three-dimensional silica gel, then the GNPs were chemisorbed onto the thiol groups of the sol–gel network and modified the kinetic barrier of this self-assembled silicate film. Cyclic voltammetry and AC impendance spectroscopy were performed to evaluate electrochemical properties of the as prepared interface. These nanoparticle inhibits the adsorption of cyt. c onto bare electrode and acts as a bridge of electron transfer between protein and electrode." @default.
- W2026486548 created "2016-06-24" @default.
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- W2026486548 date "2004-01-01" @default.
- W2026486548 modified "2023-10-15" @default.
- W2026486548 title "Direct electron transfer between cytochrome c and a gold nanoparticles modified electrode" @default.
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- W2026486548 doi "https://doi.org/10.1016/j.elecom.2003.10.004" @default.
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