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- W2026500623 abstract "The polymerization process of pyrrole has been theoretically studied using the semiempirical molecular orbital (MO) method. As a model for the polymerization, particularly representing the initial-stage reaction near the anode of the electropolymerization system, the dimerization of pyrrole is examined by the process of coupling of two cationic monomer radicals in two specifically different ways, i.e., via the σ-radical or via the π-radical. Furthermore, some related calculations are undertaken in connection with the reactions between cationic monomer and dimer radicals, and between a neutral monomer and a cationic monomer radical." @default.
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- W2026500623 date "1989-06-01" @default.
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- W2026500623 title "Theoretical study of polymerization of pyrrole" @default.
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- W2026500623 doi "https://doi.org/10.1016/0379-6779(89)90650-4" @default.
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