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- W2026535165 abstract "A theory of double potential step chronoamperometry (DPSCA) is developed for the reversible follow-up reactions represented as Ox+neightleftarrowsRed, RedoversetkundersetkKightleftarrowsZ, where k and K are the rate and the equilibrium constants of the follow-up chemical reaction, respectively. DPSCA is applied to investigate the kinetics of aquation reaction of [Co(edma)2]0 (edma: ethylenediamine-N-acetate), which is produced by electrolytic reduction of [Co(edma)2]+ in the range of pH 1.5 to 10.5. At pH 4.5,on the other hand, the hydrogen ions do not substantially contribute to the aquation and thus the rate approaches a lower limiting value (4.7×102s−1), which is in good agreement with that obtained in neutral region (4.5<pH<7), where the reverse (complex formation) reaction must be taken in to consideration. Above pH 7,..." @default.
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- W2026535165 date "1983-10-01" @default.
- W2026535165 modified "2023-09-26" @default.
- W2026535165 title "Double Potential Step Chronoamperometry for Reversible Follow-up Chemical Reactions. Application to the Aquation Kinetics of Bis(ethylenediaminemonoacetato)cobalt(II)" @default.
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- W2026535165 doi "https://doi.org/10.1246/bcsj.56.3065" @default.
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