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- W2026550151 abstract "Abstract Switchover of the diastereoselectivity was recognized by a simple selection of titanium(IV) halides in the reaction of silyl ketene acetal with a chiral imine possessing a derivative of D-(−)-phenylglycine as an auxiliary. TiF 4 effected the formation of (3 S )- β -amino ester, while TiCl 4 gave (3 R )-isomer. The β-amino esters thus obtained were converted into the corresponding β-lactams on treatment with Me 3 Al without loss of the stereochemical integrity." @default.
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- W2026550151 date "1995-07-01" @default.
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- W2026550151 title "Switchover of the diastereoselectivity induced by a simple selection of titanium(IV) halides in the addition reaction of silyl ketene acetals to a chiral imine" @default.
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- W2026550151 doi "https://doi.org/10.1016/0040-4039(95)00978-l" @default.
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