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• W2026617768 abstract "Formal [4+2] cycloaddition of cyclic enamides with imines derived from aromatic amines gave the 4-arylhexahydropyrroloquinoline skeleton in one step as mixtures of diastereoisomers. Aromatic imines derived from formaldehyde and methylglyoxalate also participated in this chemistry, with the latter favouring formation of the endo-cycloadduct. The cycloadducts derived from methylglyoxalate were unstable and fragmented to give highly substituted quinolines under both neutral and basic conditions. Imines derived from 3-cyanoacrolein also underwent cycloaddition and gave an advanced potential precursor to martinellic acid, albeit with poor diastereoselectivity." @default.
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• W2026617768 date "2001-06-01" @default.
• W2026617768 modified "2023-10-16" @default.
• W2026617768 title "Synthesis and reactivity of hexahydropyrroloquinolines" @default.
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• W2026617768 doi "https://doi.org/10.1016/s0040-4020(01)00466-5" @default.
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