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• W2026638427 abstract "Solid state wetting studies have been used to measure interfacial energies and also to estimate interfacial composition. The approach is applicable to systems where one phase forms partially wetting islands on a substrate of the other phase, and requires that the compositions of all surfaces be carefully monitored so as to allow surface energies to be corrected for adsorption effects. The CuPb interface was studied by this technique with the wetting of Pb islands on polycrystalline Cu, CuAg and CuAu polycrystalline alloys. The results show that Au lowers the CuPb interfacial energy, indicating the presence of Au segregation at the interface, whereas Ag does not change the interfacial energy. Both of the above results are also correctly predicted, quanlitatively, by a simple nearest neighbor bond model used in conjunction with the regular solution approximation. Studies of Pb on monocrystalline (001)- and (111)-oriented substrates of Cu have been carried out. These yield values of 926 and 1016 mJ/m2 for the two interfacial energies, respectively. Similar studies of Pb on (001)Cu-5 at.% Au, and (111)Cu-8 at.% Au yield interfacial energies of 889 and 959 mJ/m2, respectively, indicating interfacial excesses of Au of 0.22 and 0.34 monolayers at those interfaces." @default.
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• W2026638427 date "1993-11-01" @default.
• W2026638427 modified "2023-09-23" @default.
• W2026638427 title "A determination of interfacial energy and interfacial composition in CuPb and CuPbX alloys by solid state wetting measurements" @default.
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• W2026638427 doi "https://doi.org/10.1016/0956-7151(93)90062-w" @default.
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