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- W2026709305 abstract "The optical properties of extremely small isolated semiconductors provide a sensitive probe of the developing electronic structure in the materials. Cadmium sulfide and ${mathrm{CdS}}_{mathrm{x}}$${mathrm{Se}}_{1mathrm{ensuremath{-}}mathrm{x}}$ crystallites are precipitated in an insulating glass matrix during a secondary heat-treatment procedure. Variation in the heat treatment significantly alters the final crystallite size, enabling the examination of a size-dependent change in the observed optical-absorption edge and exciton-related photoluminescence peak energies. A diffusion-limited coarsening behavior is exhibited by the CdS crystallites precipitated from a Zn-free base glass, indicating a high degree of purity in these crystals. Growth behavior of mixed crystallites, however, indicates some stoichiometric variation with heat-treatment time. Quantum size effects measured using the CdS precipitates in the size range from 40--400 Ar{} reflect confinement primarily in the translational motion of the Wannier exciton with some slight modification of its internal electron and hole orbits." @default.
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- W2026709305 date "1988-06-15" @default.
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- W2026709305 title "Quantum size effects in optical properties of CdS-glass composites" @default.
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- W2026709305 doi "https://doi.org/10.1103/physrevb.37.10838" @default.
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