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- W2026714937 abstract "Abstract The reaction of diphenylphosphinic acid, [Ph 2 P(O)(OH)], with CoCl 2 or ZnCl 2 and 3,5‐dimethylpyrazole (DMPZ) in the presence of triethylamine affords the mononuclear phosphinates, M(Ph 2 PO 2 ) 2 (DMPZ) 2 (M= Co( 1 ), Zn( 2 )). The molecular structures of 1 and 2 reveal a tetrahedral environment around the metal. The phosphinate ligands are monoanionic and bind to the metal in a monodentate manner, while the pyrazole ligands act as neutral monodentate ligands. Intermolecular C‐H‐O and π–π interactions in 1 and 2 result in the generation of two dimensional supramolecular polymeric sheets in the solid state." @default.
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- W2026714937 date "2005-10-01" @default.
- W2026714937 modified "2023-09-27" @default.
- W2026714937 title "Mononuclear Metal Phosphinates with Ancillary Pyrazole Ligands. Synthesis and X-ray Crystal Structures of [M(Ph2PO2)2(3,5-DMPZ)2] (M = Co, Zn)" @default.
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- W2026714937 doi "https://doi.org/10.1002/zaac.200500118" @default.
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