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- W2026720536 abstract "A radiation-induced ESR center associated with nitrogen was detected in nitrogen-containing phosphate glasses. A possible structural model was given by analyzing its hyperfine (hf) structures. A 5-line X-band ESR signal was observed for the γ- or X-irradiated glasses and polycrystalline metaphosphates. It was inferred that the lineshape of the 5-line spectrum is due to hf structures produced by (1) 14N(I = 1, Ax = Ay = − 2 G, Az = 35 G) and (2) 31P(I = 1/2, A ⋍ 30 G) by isotope enrichment (15N and D) and K-band measurements. In the glasses subjected to γ-irradiation at 77 K, a PO42− radical (a hole on a non-bridging oxygen) was dominant and the hole was transferred to a nitrogen by annealing at above −50°C. These findings suggest that a hole is trapped on a nitrogen having a pyramidal structure by energetic photons and the coordination changes into trigonal planar form successively upon the hole trapping." @default.
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- W2026720536 date "1985-05-01" @default.
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- W2026720536 title "Structure of radiation-induced ESR centers in nitrogen-containing phosphate glasses" @default.
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- W2026720536 doi "https://doi.org/10.1016/0022-3093(85)90297-2" @default.
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