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• W2026748224 abstract "The diaqua(ethylisonicotinate)(pyridine-2,6-dicarboxylato)nickel(II) monohydrate complex was synthesized and characterized by spectroscopic (IR, UV/vis), X-ray diffraction and electrochemical methods. The Ni(II) ion is bonded to dipicolinate (dpc) through pyridine N atom and one O atom of each carboxylate group, two aqua ligands and N pyridine atom of ethylisonicotinate (ein), form the distorted octahedral geometry. The molecules are connected via O–H ··· O hydrogen bonds, forming motifs in three dimensional networks. IR and UV-Vis spectroscopies agree with the observed crystal structure. The voltammetric behaviour of the complex was investigated in aqueous solution by square-wave and cyclic voltammetry using a NH3/NH4Cl buffer. The square-wave voltammogram of the complex yields three reduction peaks at −0.88, −1.20 and −1.28 V. The irreversible reduction as a shoulder at −1.20 V is due to Ni-dpc-ein complex. The peak at −0.88 V corresponds to irreversible electrode process of Ni(II)-ein complex while the..." @default.
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• W2026748224 date "2008-08-10" @default.
• W2026748224 modified "2023-09-22" @default.
• W2026748224 title "Synthesis, crystal structure, spectroscopic and electrochemical properties of nickel(II) dipicolinate complex with ethylisonicotinate" @default.
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• W2026748224 doi "https://doi.org/10.1080/00958970801927076" @default.
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