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- W2026780470 abstract "The end interfacial free energies (σe) of extended-chain and folded-chain crystals of fractions of low molecular weight poly(ethylene oxide) have been estimated from measurements of melting points and crystal lamellar thicknesses. Values of σe are in the range 1 to 4kcal (mol of chains emerging)−1. It is found that σe for a given type of crystal increases as the molecular weight increases and that σe for a given polymer fraction decreases as the extent of folding increases. In that the extent of folding increases as the molecular weight increases, our findings imply a maximum value of σe for mature crystals of fractions of poly(ethylene oxide) at a molecular weight near 6000." @default.
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- W2026780470 date "1972-06-01" @default.
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- W2026780470 title "Interfacial free energy of crystals of low molecular weight poly(ethylene oxide)" @default.
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- W2026780470 doi "https://doi.org/10.1016/0032-3861(72)90001-8" @default.
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