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- W2026782755 abstract "Relaxation of angular momentum and translational velosity of linear and spherical rotators in liquid phase is considered in the framework of a simple impact model. It is assumed, that in condensed state, when a mean distance between molecules is compared with their diameters, the distribution over the duration of times between successive collisions may deviate from the Poisson one, which is characteristic of rarefied gases. Besides, formation of efficient liquid-phase cage results in preferable reflecting of the target molecule velocity. For correlation functions of angular momentum, linear velocity, for their directions and for translational and rotational energies, simple analytical expressions are obtained. A preliminary analysis shows that reproducing the characterictic negative part of correlation function time dependence, for the begining and duration of this part the model gives values that do not agree with the data of MD calculations." @default.
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- W2026782755 date "1993-11-01" @default.
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- W2026782755 title "An analytical model for impact description of liquid phase relaxation processes" @default.
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- W2026782755 doi "https://doi.org/10.1016/0167-7322(93)80065-4" @default.
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