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- W2026791359 abstract "We apply a density functional approach for arbitrary branched liquid-crystalline (LC) heteropolymers consisting of elongated rigid rods coupled through elastic joints developed in a companion paper (Wessels and Mulder 2006 J.?Phys.?Condens.?Matter.?18 9335) to a model for side-chain liquid-crystalline polymers. In this model mesogenic units are coupled through finite-length spacers to a linear backbone polymer. The stereochemical constraints imposed at the connection between spacer and backbone are explicitly modelled. Using a bifurcation analysis, analytical results are obtained for the spinodal density of the I?N transition and the variation of the degree of ordering over the various molecular parts at the instability as a function of the model parameters. We also determine the location of the crossover between oblate and prolate backbone conformations in the nematic phase." @default.
- W2026791359 created "2016-06-24" @default.
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- W2026791359 date "2006-09-29" @default.
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- W2026791359 title "Isotropic-to-nematic transition in liquid-crystalline heteropolymers: II. Side-chain liquid-crystalline polymers" @default.
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- W2026791359 doi "https://doi.org/10.1088/0953-8984/18/41/004" @default.
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