FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2026827063> ?p ?o ?g. }

• W2026827063 endingPage "1569" @default.
• W2026827063 startingPage "1559" @default.
• W2026827063 abstract "Six dichloroiron(III) complexes of 1,3-bis(2'-arylimino)isoindoline (BAIH) with various N-donor aryl groups have been characterized by spectroscopy (infrared, UV-vis), electrochemistry (cyclic voltammetry), microanalysis, and in two cases X-ray crystallography. The structurally characterized Fe(III)Cl(2)(L(n)) complexes (n = 3, L(3) = 1,3-bis(2'-thiazolylimino)isoindoline and n = 5, L(5) = 1,3-bis(4-methyl-2'-piridylimino)isoindoline) are five-coordinate, trigonal bipyramidal with the isoindoline ligands occupying the two axial and one equatorial positions meridionally. These compounds served as precursors for catechol dioxygenase models that were formed in solution upon addition of 3,5-di-tert-butylcatechol (H(2)DBC) and excess triethylamine. These adducts react with dioxygen in N,N-dimethylformamide, and the analysis of the products by chromatography and mass spectrometry showed high intradiol over extradiol selectivity (the intradiol/extradiol product ratios varied between 46.5 and 6.5). Kinetic measurements were performed by following the change in the intensity of the catecholate to iron ligand-to-metal charge transfer (LMCT) band, the energy of which is influenced by the isoindolinate-ligand (827-960 nm). In combination with electrochemical investigations the kinetic studies revealed an inverse trend between reaction rates and oxidation potentials associated with the coordinated DBC(2-). On the basis of these results, a substrate activation mechanism is suggested for this system in which the geometry of the peroxide-bridged intermediate may be of key importance in regioselectivity." @default.
• W2026827063 created "2016-06-24" @default.
• W2026827063 creator A5007150877 @default.
• W2026827063 creator A5009570331 @default.
• W2026827063 creator A5012329819 @default.
• W2026827063 creator A5043956258 @default.
• W2026827063 creator A5045488288 @default.
• W2026827063 creator A5056608406 @default.
• W2026827063 creator A5057865595 @default.
• W2026827063 date "2013-01-15" @default.
• W2026827063 modified "2023-10-09" @default.
• W2026827063 title "Iron(III) Complexes with Meridional Ligands as Functional Models of Intradiol-Cleaving Catechol Dioxygenases" @default.
• W2026827063 cites W1967687130 @default.
• W2026827063 cites W1967700647 @default.
• W2026827063 cites W1968623016 @default.
• W2026827063 cites W1968776577 @default.
• W2026827063 cites W1972314318 @default.
• W2026827063 cites W1975217371 @default.
• W2026827063 cites W1975688317 @default.
• W2026827063 cites W1977782487 @default.
• W2026827063 cites W1984349181 @default.
• W2026827063 cites W1986809611 @default.
• W2026827063 cites W1990995282 @default.
• W2026827063 cites W1991448948 @default.
• W2026827063 cites W1997110251 @default.
• W2026827063 cites W1999125811 @default.
• W2026827063 cites W2007783666 @default.
• W2026827063 cites W2009108184 @default.
• W2026827063 cites W2015799632 @default.
• W2026827063 cites W2016996977 @default.
• W2026827063 cites W2018602444 @default.
• W2026827063 cites W2020234893 @default.
• W2026827063 cites W2020551149 @default.
• W2026827063 cites W2022276904 @default.
• W2026827063 cites W2028860339 @default.
• W2026827063 cites W2029642657 @default.
• W2026827063 cites W2030262033 @default.
• W2026827063 cites W2038669999 @default.
• W2026827063 cites W2039018268 @default.
• W2026827063 cites W2042109608 @default.
• W2026827063 cites W2044179958 @default.
• W2026827063 cites W2044853032 @default.
• W2026827063 cites W2045388356 @default.
• W2026827063 cites W2047115189 @default.
• W2026827063 cites W2047183887 @default.
• W2026827063 cites W2052895859 @default.
• W2026827063 cites W2056506727 @default.
• W2026827063 cites W2057607512 @default.
• W2026827063 cites W2057773123 @default.
• W2026827063 cites W2060588342 @default.
• W2026827063 cites W2061289916 @default.
• W2026827063 cites W2066248975 @default.
• W2026827063 cites W2068040666 @default.
• W2026827063 cites W2068411327 @default.
• W2026827063 cites W2068882027 @default.
• W2026827063 cites W2071556921 @default.
• W2026827063 cites W2075122538 @default.
• W2026827063 cites W2082847413 @default.
• W2026827063 cites W2083280040 @default.
• W2026827063 cites W2083631371 @default.
• W2026827063 cites W2088356379 @default.
• W2026827063 cites W2091110698 @default.
• W2026827063 cites W2092054562 @default.
• W2026827063 cites W2105249240 @default.
• W2026827063 cites W2110352313 @default.
• W2026827063 cites W2111660014 @default.
• W2026827063 cites W2116160578 @default.
• W2026827063 cites W2118660903 @default.
• W2026827063 cites W2119992321 @default.
• W2026827063 cites W2131350133 @default.
• W2026827063 cites W2146675794 @default.
• W2026827063 cites W2165201155 @default.
• W2026827063 cites W2484707817 @default.
• W2026827063 doi "https://doi.org/10.1021/ic302378r" @default.
• W2026827063 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23320898" @default.
• W2026827063 hasPublicationYear "2013" @default.
• W2026827063 type Work @default.
• W2026827063 sameAs 2026827063 @default.
• W2026827063 citedByCount "34" @default.
• W2026827063 countsByYear W20268270632013 @default.
• W2026827063 countsByYear W20268270632014 @default.
• W2026827063 countsByYear W20268270632015 @default.
• W2026827063 countsByYear W20268270632016 @default.
• W2026827063 countsByYear W20268270632017 @default.
• W2026827063 countsByYear W20268270632020 @default.
• W2026827063 countsByYear W20268270632021 @default.
• W2026827063 countsByYear W20268270632022 @default.
• W2026827063 countsByYear W20268270632023 @default.
• W2026827063 crossrefType "journal-article" @default.
• W2026827063 hasAuthorship W2026827063A5007150877 @default.
• W2026827063 hasAuthorship W2026827063A5009570331 @default.
• W2026827063 hasAuthorship W2026827063A5012329819 @default.
• W2026827063 hasAuthorship W2026827063A5043956258 @default.
• W2026827063 hasAuthorship W2026827063A5045488288 @default.
• W2026827063 hasAuthorship W2026827063A5056608406 @default.
• W2026827063 hasAuthorship W2026827063A5057865595 @default.
• W2026827063 hasConcept C108204754 @default.
• W2026827063 hasConcept C116569031 @default.

• next