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- W2026830161 abstract "Abstract For the purpose of exploring a new reaction of acylzirconocene chloride as an acyl anion donor, Cu(I)-catalyzed cross-coupling and conjugate addition reactions of acylzirconocene chloride were studied. The coupling reaction with allylic or propargylic halides efficiently proceeded to yield β,γ-unsaturated ketone or allenyl ketone derivatives, respectively. The conjugated addition reaction to α,β-enones was carried out in the presence of 2 equiv. of BF 3 ·OEt 2 giving 1,4-diketone compounds." @default.
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- W2026830161 date "2002-12-01" @default.
- W2026830161 modified "2023-10-12" @default.
- W2026830161 title "Copper(I)-catalyzed reaction of acylzirconocene chloride: cross-coupling and conjugate addition" @default.
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- W2026830161 doi "https://doi.org/10.1016/s0040-4020(02)01422-9" @default.
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