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- W2026886546 abstract "CD spectral studies show that kinetic diastereotopic discrimination occurs in the reaction of (R,S)-[Fe(CO)3(l-5-η-2-MeOC6H6)]+ (I) with (R)-(+)589-1-phenylethylamine (II) in CH3CN. This process involves initial attack by the amine at the C(5) position of the dienyl ring to give diastereometric cations of formula [Fe(CO)3 {PhCH(Me)NH2·C6H6OMe}]+ (IIIa, IIIb). Subsequent room temperature epimerization of an equimolar mixture of these two diastereomers is excluded by CD and 1H NMR experiments. Addition of further amine (I/II molar ratio of 1/2) causes deprotonation of the amine substituents in (IIIa, IIIb) to give the corresponding neutral diastereomers (IVa, IVb)." @default.
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- W2026886546 date "1982-01-01" @default.
- W2026886546 modified "2023-10-13" @default.
- W2026886546 title "Chiral discrimination in organometallic systems. Reaction of [Fe(CO)3(1-5-η-2-MeOC6H6)]+ with (R)-(+)589-1- phenylethylamine" @default.
- W2026886546 cites W2024555439 @default.
- W2026886546 doi "https://doi.org/10.1016/s0022-328x(00)86855-2" @default.
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