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- W2026937568 abstract "The crystal structure and magnetic property of the title compound [Mn(L)H2O]2(ClO4)2 are described. The complex crystallizes in the triclinic space group P1 with formula = MnClO7N2C15H20, a = 11.615(4), b = 11.955(4), c = 7.753(2) Å, α = 104.65(2), β = 111.84(3), γ = 63.64(2)°, V = 890.5(6) Å3 and Z = 2. The complex consists of a binuclear structure bridged by two phenoxo oxygen atoms O(1) and O(1)* of the quadridentate ligands in an out-of-plane mode, where the binuclear structure has a crystallographical center of symmetry, and the bond distances of MnMn* and MnO(1)* are 3.318(1) and 2.305(2) Å, respectively. The magnetic susceptibility data (4.2–300 K) showed a maximum at 11 K and were closely reproduced by the spin-Hamiltonian H = 2JS1·S2 with J = −1.68 cm−1 and g = 2.01. The deviation of the observed values from the theoretical curve in the lower temperature region is due to the zerofield splitting term. The X-band ESR spectrum in frozen dichloromethane solution at 20 K showed a broad signal at 900 G and a multiline signal at 3300 G." @default.
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- W2026937568 title "Crystal structure and magnetic property of the binuclear manganese(III) complex [Mn(L)H2O]2(ClO4)2(L N-(acetylaceto nylidene)-N′-(α-methylsalicylidene)-ethylenediamine)" @default.
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- W2026937568 doi "https://doi.org/10.1016/s0020-1693(00)80579-4" @default.
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