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- W2026952008 abstract "A novel process called Liquid Source Misted Chemical Deposition (LSMCD) was used to synthesize Al-doped LiMn2O4 cathode films for Lithium microbatteries. The cathode films were characterized by XRD, SEM, cyclic volatmmetry, and charge/discharge test. LiMn1.8Al0.2O4 film crystallized at 800 °C in rapid thermal annealing (RTA) for 5 min under oxygen atmosphere exhibited more improved electrochemical rechargeability than spinel LiMn2O4 film because the substitution of Al3+ for Mn3+ increased MnO bonding strength in the spinel framework and suppressed the two-phase behavior of the unsubstituted spinel during the intercalation/deintercalation that is the origin of the failure mechanism in the 4 V region. As a result, LiMn1.8Al0.2O4 film showed an initial discharge capacity of 52 μAh/cm2 μm and no capacity fade over 100 cycles." @default.
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- W2026952008 date "2003-12-01" @default.
- W2026952008 modified "2023-10-10" @default.
- W2026952008 title "Characterization of Al-doped spinel LiMn2O4 thin film cathode electrodes prepared by Liquid Source Misted Chemical Deposition (LSMCD) technique" @default.
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- W2026952008 doi "https://doi.org/10.1016/s0013-4686(03)00608-x" @default.
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