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- W2026954653 abstract "Complex formation of copper(II) with decanoic acid (HA) has been studied by potentiometric measurement in 1,4-dioxane-water mixtures at a constant ionic concentration of 0.1 mol dm−3 (Na, H)ClO4 and at 25°C. The experimental data can be interpreted with the formation of CuA+, CuA2 and Cu2A4. The dimerization constant formulated as: was found to be log Kdim = 3.75, 4.02 and 4.26 for 0.3, 0.4 and 0.5 mole fractions of dioxane, respectively. Absorbances at 373 and 670 nm are interpreted with the aid of the formation constants determined by potentiometry. Solvent effect on the dimerization of the monomeric copper(II) decanoate is discussed on the basis of selective solvation of CuA2 and Cu2A4 with water molecules." @default.
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- W2026954653 date "1985-01-01" @default.
- W2026954653 modified "2023-09-23" @default.
- W2026954653 title "Dimerization of copper(II) decanoate in 1,4-dioxane-water mixed solvents" @default.
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- W2026954653 doi "https://doi.org/10.1016/s0277-5387(00)87017-5" @default.
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