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• W2026957788 abstract "Ferrocene derivatives bearing podand dipeptide chains (-l-Ala-l-Pro-OR; R=Me, Et, Pr, CH2Ph) were synthesized and characterized by spectroscopy and X-ray crystallography. The ferrocenes exhibited Cotton effects in the CD spectra to indicate an ordered conformation, which is considered to depend on the intramolecular hydrogen bonds between CO (Ala) and NH (Ala of another strand). The X-ray structural analysis also revealed that such identical intramolecular hydrogen bonding is present in the solid state to orient the podand dipeptide chains in the same direction. A helical molecular arrangement in the crystal packing was observed in the case of the methyl and ethyl esters to form the ferrocenic and hydrophobic columns." @default.
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• W2026957788 date "1999-10-01" @default.
• W2026957788 modified "2023-09-27" @default.
• W2026957788 title "Characterization of ferrocene derivatives bearing podand dipeptide chains (-l-Ala-l-Pro-OR)" @default.
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• W2026957788 doi "https://doi.org/10.1016/s0022-328x(99)00301-0" @default.
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