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- W2026972103 abstract "Abstract The generation of the anion is described; this species reacts with a range of electrophiles in good yield, according to the Scheme. The adducts display synthetic utility; the adduct with chlorodimethylphenylsilane allows stereocontrolled replacement of the fluorine anti-to the silicon with an alkyl group. The adduct with tributyltin chloride serves as a convenient source for the anion under amine-free conditions while the aldehyde adducts, after suitable derivatisation undergo a range of sigmatropic rearrangements leading to interesting difluoromethylene-containing compounds. The anion represents a significant addition to the pool of fluorine-containing building blocks and approaches to fluorine-containing natural product analogues using this chemistry will be described." @default.
- W2026972103 created "2016-06-24" @default.
- W2026972103 creator A5035070593 @default.
- W2026972103 date "1991-09-01" @default.
- W2026972103 modified "2023-09-27" @default.
- W2026972103 title "Generation and trapping of a stabilised difluorovinyl anion" @default.
- W2026972103 cites W2166065087 @default.
- W2026972103 doi "https://doi.org/10.1016/s0022-1139(00)83575-7" @default.
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