FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2026972799> ?p ?o ?g. }

• W2026972799 endingPage "751" @default.
• W2026972799 startingPage "744" @default.
• W2026972799 abstract "A framework en-Mg2(dobpdc) (1-en; en = ethylenediamine) functionalized with the primary amine en was prepared via postmodification. From synchrotron PXRD data, it is revealed that the cell parameters change upon grafting of en and CO2 uptake. The adsorbed CO2 amount of 1-en is 4.57 mmol g−1 (16.7 wt%) at 25 °C and 1 bar and decreases to 3.00 mmol g−1 (11.7 wt%) at 150 °C. Noticeably, 1-en shows a significant CO2 uptake (3.62 mmol g−1, 13.7 wt%) at 0.15 bar, which is comparable to the CO2 partial pressure of a post-combustion flue gas. The CO2 capacity of 1-en at 0.39 mbar, close to atmospheric CO2 concentration, is 2.83 mmol g−1 (11.1 wt%), which marks the highest amount among MOFs. The isosteric heat of adsorption (−Qst) of 1-en in CO2 capture corresponds to 49–51 kJ mol−1, which is supported by DFT calculations (−52.8 kJ mol−1). These results suggest that the adsorption of CO2 onto the free amines of en leads to the formation of a carbamic acid. Adsorption–desorption cyclings of CO2 at the real dilute concentrations of air and flue gas are established with almost retaining CO2 capacities, which could provide superior potential for practical application in CO2 capture. The adsorption rate of CO2 in 1-en exceeds that in some other tested porous materials. The recyclability in CO2 uptake for 1-en is maintained even after exposure to humidity." @default.
• W2026972799 created "2016-06-24" @default.
• W2026972799 creator A5005983667 @default.
• W2026972799 creator A5007459616 @default.
• W2026972799 creator A5035536938 @default.
• W2026972799 creator A5042766411 @default.
• W2026972799 creator A5052171305 @default.
• W2026972799 creator A5067470445 @default.
• W2026972799 creator A5067483266 @default.
• W2026972799 creator A5088652060 @default.
• W2026972799 date "2014-01-01" @default.
• W2026972799 modified "2023-10-17" @default.
• W2026972799 title "Diamine-functionalized metal–organic framework: exceptionally high CO₂capacities from ambient air and flue gas, ultrafast CO₂uptake rate, and adsorption mechanism" @default.
• W2026972799 cites W1970095940 @default.
• W2026972799 cites W1976408176 @default.
• W2026972799 cites W1983902012 @default.
• W2026972799 cites W1985354366 @default.
• W2026972799 cites W1996369650 @default.
• W2026972799 cites W2000302001 @default.
• W2026972799 cites W2002799357 @default.
• W2026972799 cites W2007082361 @default.
• W2026972799 cites W2007489056 @default.
• W2026972799 cites W2009368971 @default.
• W2026972799 cites W2010815720 @default.
• W2026972799 cites W2011661984 @default.
• W2026972799 cites W2022165195 @default.
• W2026972799 cites W2024685013 @default.
• W2026972799 cites W2047480702 @default.
• W2026972799 cites W2059420540 @default.
• W2026972799 cites W2065500091 @default.
• W2026972799 cites W2073662703 @default.
• W2026972799 cites W2074445234 @default.
• W2026972799 cites W2076949647 @default.
• W2026972799 cites W2079597466 @default.
• W2026972799 cites W2082846892 @default.
• W2026972799 cites W2086782801 @default.
• W2026972799 cites W2091161882 @default.
• W2026972799 cites W2091280238 @default.
• W2026972799 cites W2092420325 @default.
• W2026972799 cites W2094145140 @default.
• W2026972799 cites W2099651626 @default.
• W2026972799 cites W2101187042 @default.
• W2026972799 cites W2104943417 @default.
• W2026972799 cites W2108623890 @default.
• W2026972799 cites W2114234483 @default.
• W2026972799 cites W2130360607 @default.
• W2026972799 cites W2136717834 @default.
• W2026972799 cites W2136939531 @default.
• W2026972799 cites W2140743414 @default.
• W2026972799 cites W2149881251 @default.
• W2026972799 cites W2151993017 @default.
• W2026972799 cites W2313722618 @default.
• W2026972799 cites W2317747468 @default.
• W2026972799 cites W2326670558 @default.
• W2026972799 cites W2327021338 @default.
• W2026972799 cites W2328088879 @default.
• W2026972799 cites W2329367218 @default.
• W2026972799 cites W2332893944 @default.
• W2026972799 cites W3143879557 @default.
• W2026972799 doi "https://doi.org/10.1039/c3ee42328j" @default.
• W2026972799 hasPublicationYear "2014" @default.
• W2026972799 type Work @default.
• W2026972799 sameAs 2026972799 @default.
• W2026972799 citedByCount "237" @default.
• W2026972799 countsByYear W20269727992014 @default.
• W2026972799 countsByYear W20269727992015 @default.
• W2026972799 countsByYear W20269727992016 @default.
• W2026972799 countsByYear W20269727992017 @default.
• W2026972799 countsByYear W20269727992018 @default.
• W2026972799 countsByYear W20269727992019 @default.
• W2026972799 countsByYear W20269727992020 @default.
• W2026972799 countsByYear W20269727992021 @default.
• W2026972799 countsByYear W20269727992022 @default.
• W2026972799 countsByYear W20269727992023 @default.
• W2026972799 crossrefType "journal-article" @default.
• W2026972799 hasAuthorship W2026972799A5005983667 @default.
• W2026972799 hasAuthorship W2026972799A5007459616 @default.
• W2026972799 hasAuthorship W2026972799A5035536938 @default.
• W2026972799 hasAuthorship W2026972799A5042766411 @default.
• W2026972799 hasAuthorship W2026972799A5052171305 @default.
• W2026972799 hasAuthorship W2026972799A5067470445 @default.
• W2026972799 hasAuthorship W2026972799A5067483266 @default.
• W2026972799 hasAuthorship W2026972799A5088652060 @default.
• W2026972799 hasConcept C111472728 @default.
• W2026972799 hasConcept C120665830 @default.
• W2026972799 hasConcept C121332964 @default.
• W2026972799 hasConcept C127413603 @default.
• W2026972799 hasConcept C138885662 @default.
• W2026972799 hasConcept C150394285 @default.
• W2026972799 hasConcept C167206829 @default.
• W2026972799 hasConcept C178596936 @default.
• W2026972799 hasConcept C178790620 @default.
• W2026972799 hasConcept C179104552 @default.
• W2026972799 hasConcept C179366358 @default.
• W2026972799 hasConcept C185592680 @default.
• W2026972799 hasConcept C192562407 @default.
• W2026972799 hasConcept C2780871995 @default.
• W2026972799 hasConcept C42360764 @default.

• next