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- W2026986705 abstract "Abstract Liquid phase epitaxy (LPE) growth mechanisms and the effects of impurities were investigated using a new method. It was demonstrated that the Volmer–Weber mechanism operates on (0 0 1), a K face according to the Hartman–Perdok theory, whereas the Frank–van der Merve mechanism operates on (1 1 0), an F face, and on (1 1 1), an S face. It was also confirmed that tri-valent cations with ionic radii close to Ti4+ ions transform the character of the (1 1 1) face from an S face to a K face, producing a greatly accelerated growth rate in the c-axis direction, whereas the same impure ions reduce the growth rate on the (1 1 0) face. This difference is well represented in the change of the surface morphologies of the respective faces. The observed morphological changes are interpreted on the assumption that oxygen ions around Ti4+ ions are destabilized by the adsorption of tri-valent cations, leading to breaking the PBC in the (1 1 1) face." @default.
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- W2026986705 date "2001-09-01" @default.
- W2026986705 modified "2023-09-30" @default.
- W2026986705 title "Investigations on the growth and morphology of TiO2 in the TiO2–Na2B4O7 system with and without impurities using a new LPE method" @default.
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