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- W2026987699 abstract "1,4-Anhydro-3-O-benzyl-2,5-dideoxy-4a-carba-DL-erythro-hex-1-enitol-uronic acid (5) was transformed by chain degradation under suitable protection and reaction with m-CPBA into 5-O-acetyl-1,2-anhydro-4a-carba-α-DL-xylofuranose (37). Replacement of the triflate by azide gave 5-O-acetyl-1,2-anhydro-3-azido-3-deoxy-4a-carba-α-DL-ribofuranose (39), a versatile intermediate for the preparation of 3-azido- and 3-amino-4a-carbanucleosides. Similarly via 5-deoxy-4a-carba-α-DL-xylo-hexofuranurono-6,3-lactone (2) 5-O-acetyl-3-azido-3-deoxy-1,2-isopropylidene-4a-carba-α-DL-ribofuranose (19) was prepared which can serve for the same purpose." @default.
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- W2026987699 title "A novel access to derivatives of 3-azido-3-deoxy-4a-carba-α-DL-ribofuranose, potential intermediates for the synthesis of carbachryscandin and carbapuromycin" @default.
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