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- W2027026967 abstract "We report ab initio results at the Hartree-Fock/6–31G level for the energetics of the codon-anticodon pairing in tRNAPhe. We have employed a molecular dynamics protocol in order to relax the studied crystallographic structure. Electrostatic potentials due to the presence of the hypermodified Y base and a guanine base in position 37 of the anticodon loop are compared. The results of the electrostatic potentials on the planes containing the molecules of the complementary codon bases UUC, indicate a strong energetic stabilization when a Y base is present, in comparison to the substitution by a guanine base. The present results provide some molecular data on the energetics of the codon-anticodon pairing mechanism and are related to experimental studies which suggest that hypermodification in tRNAs contribute to the regulation of gene expression." @default.
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- W2027026967 date "1998-03-01" @default.
- W2027026967 modified "2023-10-17" @default.
- W2027026967 title "The hypermodified Y base electrostatic contribution to the energetics of the codon-anticodon pairing in tRNAPhe" @default.
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- W2027026967 doi "https://doi.org/10.1016/s0166-1280(97)00198-x" @default.
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