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- W2027090233 abstract "The characteristically low conversion in the oxidation of cyclohexane to form cyclohexanol and cyclohexanone requires significant recovery work via distillation. In this study, new isothermal vapor−liquid equilibria (VLE) are presented for the cyclohexane + cyclohexanone binary system. Measurements were performed at temperatures of (423, 444, 464, and 484) K, using an apparatus based on the “static−analytic” method, with two ROLSI pneumatic capillary samplers. The generated data are correlated using two equations of state, namely, the Peng−Robinson coupled with the Wong−Sandler mixing rules and the perturbed-chain statistical associating fluid theory (SAFT) with a dipolar contribution by Jog and Chapman. While both models perform reasonably well in describing the phase equilibria, the Peng−Robinson is slightly better than the perturbed-chain SAFT equation of state and tends to be more easily implemented in industrial process simulators." @default.
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- W2027090233 date "2010-08-09" @default.
- W2027090233 modified "2023-09-24" @default.
- W2027090233 title "Vapor−Liquid Equilibrium Measurements and Modeling for Cyclohexane + Cyclohexanone" @default.
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- W2027090233 doi "https://doi.org/10.1021/je100474b" @default.
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