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• W2027090886 endingPage "10101" @default.
• W2027090886 startingPage "10096" @default.
• W2027090886 abstract "It has previously been shown that the entanglement molecular weight (Me) and the plateau modulus ( ) of flexible polymers can be correlated to the unperturbed chain dimension, 〈R2〉0/M, chain density (ρ) via the use of the packing length (p), which is defined as the volume of a chain divided by its mean square end to end distance. For polyolefins and co-polyolefins where 〈R2〉0/M remains unmeasured a method is presented herein where knowledge of the average molecular weight per backbone bond (mb) allows and thus Meto be estimated. This is particularly valuable for the case of polyolefin copolymers where the melt chain dimensions (and thus the packing length) are unknown." @default.
• W2027090886 created "2016-06-24" @default.
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• W2027090886 date "2002-11-27" @default.
• W2027090886 modified "2023-10-17" @default.
• W2027090886 title "Prediction of Melt State Poly(α-olefin) Rheological Properties: The Unsuspected Role of the Average Molecular Weight per Backbone Bond" @default.
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• W2027090886 doi "https://doi.org/10.1021/ma025659z" @default.
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