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- W2027164651 abstract "Alkyl dihydrogenphosphates, containing alkyl groups of ethyl, butyl, hexyl, and octyl, were synthesized and allowed to react with calcium carbonate powder in an aqueous medium. The reactions were monitored by pH of the medium. The analyses of the reaction products brought to the conclusion that alkyl dihydrogenphosphates containing small alkyl groups react with the calcium carbonate to form monobasic calcium alkyl phosphates, while alkyl dihydrogenphosphates carrying large alkyl groups afford dibasic calcium alkyl phosphates. The results of thermal and infrared spectral analyses of the calcium salts of hexyl and octyl phosphates also supported the reaction scheme proposed. The calcium carbonates, treated with larger alkyl dihydrogenphosphates, were found to exhibit hydrophobicity. From scanning electron micrographic observations, this phenomenon was attributed to the deposition of the calcium alkyl phosphates, produced in the reaction mixture, onto the calcium carbonate surface." @default.
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- W2027164651 date "1981-08-01" @default.
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- W2027164651 title "Topochemical reaction of calcium carbonate and alkyl dihydrogenphosphate" @default.
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- W2027164651 doi "https://doi.org/10.1016/0021-9797(81)90372-6" @default.
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