Matches in SemOpenAlex for { <https://semopenalex.org/work/W2027165780> ?p ?o ?g. }
- W2027165780 endingPage "95" @default.
- W2027165780 startingPage "87" @default.
- W2027165780 abstract "The synthesis and photochemical characterization of a covalently bonded palladium meso-sulfophenylporphyrin-poly(vinyl alcohol)polymer ( PVA - PdTPPS ), made via reaction of the chlorosulfonyl derivative of Pd meso-tetrakis-phenylporphyrin with the alcohol group of the polymer to form the sulfonate ester, is described. Absorption, emission and phosphorescence lifetime data are reported. In both the solid film and in aqueous solution phosphorescence decays in the absence of oxygen are non-monoexponential and suggest heterogeneity in the decay and oxygen quenching kinetics. As a solid film there is very little phosphorescence quenching by oxygen at moderate pressures of O 2 (0-30 Torr), but in aqueous solution oxygen quenches at a rate of 7.5 (±0.5) × 10 8 M . s −1 . The synthetic route described is versatile enough to be used with a variety of metalloporphyrins and polymers and this allows the possibility of extensive tuning in terms of lumophore lifetime, polarity, solubility, location in heterogeneous media, and compatibility with other polymers." @default.
- W2027165780 created "2016-06-24" @default.
- W2027165780 creator A5010136399 @default.
- W2027165780 creator A5024552137 @default.
- W2027165780 creator A5047738872 @default.
- W2027165780 creator A5059855253 @default.
- W2027165780 creator A5060879175 @default.
- W2027165780 creator A5061777028 @default.
- W2027165780 creator A5076757579 @default.
- W2027165780 date "2006-02-01" @default.
- W2027165780 modified "2023-09-23" @default.
- W2027165780 title "Synthesis and photophysical properties of a covalently bonded palladiummeso-sulfophenylporphyrin-poly(vinyl alcohol)polymer with potential applications as an oxygen sensor" @default.
- W2027165780 cites W1613111302 @default.
- W2027165780 cites W1964222644 @default.
- W2027165780 cites W1965951679 @default.
- W2027165780 cites W1967317440 @default.
- W2027165780 cites W1972215607 @default.
- W2027165780 cites W1975663171 @default.
- W2027165780 cites W1975672349 @default.
- W2027165780 cites W1982334871 @default.
- W2027165780 cites W1990352731 @default.
- W2027165780 cites W1991979058 @default.
- W2027165780 cites W1995082863 @default.
- W2027165780 cites W1996039779 @default.
- W2027165780 cites W2008558867 @default.
- W2027165780 cites W2017220615 @default.
- W2027165780 cites W2019825048 @default.
- W2027165780 cites W2022952426 @default.
- W2027165780 cites W2026052685 @default.
- W2027165780 cites W2029580926 @default.
- W2027165780 cites W2029763383 @default.
- W2027165780 cites W2032334841 @default.
- W2027165780 cites W2034621683 @default.
- W2027165780 cites W2035930794 @default.
- W2027165780 cites W2074138089 @default.
- W2027165780 cites W2077328956 @default.
- W2027165780 cites W2083250568 @default.
- W2027165780 cites W2089161013 @default.
- W2027165780 cites W2093423090 @default.
- W2027165780 cites W2118009826 @default.
- W2027165780 cites W2147512237 @default.
- W2027165780 cites W2153184843 @default.
- W2027165780 cites W3021584963 @default.
- W2027165780 cites W411954668 @default.
- W2027165780 cites W49981767 @default.
- W2027165780 doi "https://doi.org/10.1142/s1088424606000119" @default.
- W2027165780 hasPublicationYear "2006" @default.
- W2027165780 type Work @default.
- W2027165780 sameAs 2027165780 @default.
- W2027165780 citedByCount "4" @default.
- W2027165780 countsByYear W20271657802012 @default.
- W2027165780 crossrefType "journal-article" @default.
- W2027165780 hasAuthorship W2027165780A5010136399 @default.
- W2027165780 hasAuthorship W2027165780A5024552137 @default.
- W2027165780 hasAuthorship W2027165780A5047738872 @default.
- W2027165780 hasAuthorship W2027165780A5059855253 @default.
- W2027165780 hasAuthorship W2027165780A5060879175 @default.
- W2027165780 hasAuthorship W2027165780A5061777028 @default.
- W2027165780 hasAuthorship W2027165780A5076757579 @default.
- W2027165780 hasConcept C121332964 @default.
- W2027165780 hasConcept C121745418 @default.
- W2027165780 hasConcept C155574463 @default.
- W2027165780 hasConcept C178790620 @default.
- W2027165780 hasConcept C181817918 @default.
- W2027165780 hasConcept C184651966 @default.
- W2027165780 hasConcept C185592680 @default.
- W2027165780 hasConcept C188027245 @default.
- W2027165780 hasConcept C2780666587 @default.
- W2027165780 hasConcept C2781066024 @default.
- W2027165780 hasConcept C521977710 @default.
- W2027165780 hasConcept C540031477 @default.
- W2027165780 hasConcept C62520636 @default.
- W2027165780 hasConcept C75473681 @default.
- W2027165780 hasConcept C91881484 @default.
- W2027165780 hasConceptScore W2027165780C121332964 @default.
- W2027165780 hasConceptScore W2027165780C121745418 @default.
- W2027165780 hasConceptScore W2027165780C155574463 @default.
- W2027165780 hasConceptScore W2027165780C178790620 @default.
- W2027165780 hasConceptScore W2027165780C181817918 @default.
- W2027165780 hasConceptScore W2027165780C184651966 @default.
- W2027165780 hasConceptScore W2027165780C185592680 @default.
- W2027165780 hasConceptScore W2027165780C188027245 @default.
- W2027165780 hasConceptScore W2027165780C2780666587 @default.
- W2027165780 hasConceptScore W2027165780C2781066024 @default.
- W2027165780 hasConceptScore W2027165780C521977710 @default.
- W2027165780 hasConceptScore W2027165780C540031477 @default.
- W2027165780 hasConceptScore W2027165780C62520636 @default.
- W2027165780 hasConceptScore W2027165780C75473681 @default.
- W2027165780 hasConceptScore W2027165780C91881484 @default.
- W2027165780 hasIssue "02" @default.
- W2027165780 hasLocation W20271657801 @default.
- W2027165780 hasOpenAccess W2027165780 @default.
- W2027165780 hasPrimaryLocation W20271657801 @default.
- W2027165780 hasRelatedWork W1986673804 @default.
- W2027165780 hasRelatedWork W1999360603 @default.
- W2027165780 hasRelatedWork W2016032392 @default.
- W2027165780 hasRelatedWork W2041325465 @default.
- W2027165780 hasRelatedWork W2048328013 @default.