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- W2027240482 abstract "Expression for the corrections describing the effect of viscous flow and thermal flux on the rate of chemical reaction have been derived for the reaction A + A = B + C described by Prigogine-Xhrouet and Present. These corrections are calculated for the velocity distribution function up to the second-order approximation for the Chapman-Enskog solution of the Boltzmann equation. These corrections are shown to be the same as those which would follow after application of the method of linearized-moments equations described by Eu and Li. The effects of viscous flow and thermal flux are presented as functions of activation energy of chemical reaction, temperature, density, coefficients of shear viscosity of thermal conductivity, and relevant gradients of mean molecular velocity or temperature. It is pointed out that for very slow reactions and for very large gradients (e.g. in shock waves) these effects can be quite significant." @default.
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- W2027240482 date "1986-11-01" @default.
- W2027240482 modified "2023-09-27" @default.
- W2027240482 title "The effect of viscous flow and thermal flux on the rate of chemical reaction in dilute gases" @default.
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- W2027240482 doi "https://doi.org/10.1016/0301-0104(86)87053-7" @default.
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