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- W2027251019 abstract "Franck-Condon analyses are applied to the high-resolution photoelectron spectra of C2H2 and C2D2. From the first photoelectron bands, the CH and CC bond lengths are found to be respectively 1.076 and 1.250 Å for C2H2+ and 1.080 and 1.247 Å for C2D2+ in the X 2Πu state. Results obtained are compared with those by previous workers. As for the third photoelectron bands, simulated spectra of acetylenes agree well with observed ones. The CH and CC bond lengths thus deduced for the B 2Σu+ state have values of respectively 1.271 and 1.191 Å for C2H2+ and 1.276 and 1.178 Å for C2D2+. The long CH bond length obtained for the acetylene ions is discussed." @default.
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- W2027251019 date "1990-05-01" @default.
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- W2027251019 title "Ionic geometries of acetylene in the X 2Πu and B 2Σu+ ionic states" @default.
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- W2027251019 doi "https://doi.org/10.1016/0009-2614(90)85162-6" @default.
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