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• W2027275050 abstract "The intensity of the indirect chemiluminescence of ternary solutions containing tetramethyl-1,2-dioxetane (TMD) and 9-bromoanthracene (BA) or 9,10-dichloroanthracene (DCA) in toluene was investigated as a function of acceptor concentration and pressure at 40 °C. The results are discussed in connection with the pressure dependence of the fluorescence of both acceptors, which was determined in this study, and the pressure dependence of the rate of decomposition of TMD reported earlier. It is shown that the energy transfer from triplet acetone to BA and DCA is a spin-allowed triplet—triplet process, as was found for the energy transfer to 9,10-dibromoanthracene (DBA). A comparison of the intensities of chemiluminescence, extrapolated to infinitely high concentrations, leads to the determination of the yields of intersystem crossing from the second excited triplet state T2 to the singlet state S1 for DBA, BA and DCA, respectively." @default.
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• W2027275050 date "1978-01-01" @default.
• W2027275050 modified "2023-10-15" @default.
• W2027275050 title "The energy transfer from triplet state acetone to 9-bromoanthracene and 9,10-dichloroanthracene: an investigation under high pressure" @default.
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• W2027275050 doi "https://doi.org/10.1016/0047-2670(78)80023-9" @default.
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