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- W2027318374 abstract "Using a CCD imaging detector of broad spectral sensitivity, the chemiluminescent (CL) emission wavelength of accelerated thermal oxidation of polypropylene has been found to depend on the extent of oxidation of the material. Initial Chemiluminescence occurs mainly below 385 nm, and this is consistent with a bimolecular peroxy radical termination as the source of the emitting triplet ketone. The maximum emission shifts to longer wavelengths as further oxidation of the primary products of degradation results in phosphorescent carbonyl groups of lower energy than an isolated ketone. Results indicate that this secondary emitting species is α,β-unsaturated carbonyls, thought to be formed by the same termination mechanism." @default.
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- W2027318374 date "1996-02-01" @default.
- W2027318374 modified "2023-10-14" @default.
- W2027318374 title "Chemiluminescence from polypropylene. Part 2: The emission wavelengths during prolonged oxidation" @default.
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- W2027318374 doi "https://doi.org/10.1016/0141-3910(95)00192-1" @default.
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