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- W2027321119 abstract "Abstract We have measured the reflectivity spectra of stages 1 and 2 graphite intercalated with KHg amalgam (KHgC4 and KHgC8) from 0.5–6eV, and compared them to the corresponding stages 1 and 2 binary compounds, KC8 and KC24. Plasma edges for the ternaries appear at about the same energies as in the binaries, but differences are observed in the reflectivity values at the minima. Kramers-Kroenig analysis yields thresholds for the onset of interband transitions at 1.3eV and 1.2eV for KHgC4 and KHgC8, compared to 2.7eV and 1.7eV for KC8 and KC24. The thresholds are explained in terms of interband transitions in the mercurographitides involving the Hg levels. A model for these transitions is presented based on the Mott metal-semiconductor transition in mercury. This model is shown to be consistent with the hypothesis that the mercury layers are negatively charged." @default.
- W2027321119 created "2016-06-24" @default.
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- W2027321119 date "1982-10-01" @default.
- W2027321119 modified "2023-09-24" @default.
- W2027321119 title "Optical properties of stages 1 and 2 potassium mercurographitides" @default.
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- W2027321119 doi "https://doi.org/10.1016/0038-1098(82)90870-5" @default.
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