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- W2027367794 abstract "The design and facile green synthesis of supported metal-engineered nanoparticles with efficient catalytic activity has significant industrial importance. A biosynthetic and ecofriendly one-step reduction strategy has been developed through the protein-mediated in vitro biosynthesis of AgNPs on the surface of nanosilica. The as-synthesized silver nanoparticles supported on nanosilica (Ag@Nanosilica) were characterized by field emission scanning electron microscopy (FESEM), energy dispersive X-ray (EDXA) elemental mapping, high resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and thermogravimetric analysis (TGA). The spectroscopic and electron microscopic studies demonstrated that the immobilized protein on the nanosilica surface served as a reducing, capping and stabilising agent, while sodium dodecyl sulfate polyacrylamide gel electrophoresis analysis revealed that the three proteins of 48, 38 and 36 kDa participated in the formation of Ag@Nanosilica material. The formation mechanism of AgNPs on nanosilica explained the origin of the biomineralization of metal nanoparticles in nature. The novel reusable Ag@Nanosilica exhibited enhanced catalytic activity for the hydrogenation of a model compound, namely, 4-nitrophenol. Overall our results will help to understand metal nanoparticle formation in the Earth’s crust and aid the design of “green” syntheses of novel nanoreactors." @default.
- W2027367794 created "2016-06-24" @default.
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- W2027367794 date "2013-01-01" @default.
- W2027367794 modified "2023-09-30" @default.
- W2027367794 title "Bio-inspired fabrication of silver nanoparticles on nanostructured silica: characterization and application as a highly efficient hydrogenation catalyst" @default.
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- W2027367794 doi "https://doi.org/10.1039/c3gc40310f" @default.
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