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- W2027374034 abstract "New experimental and theoretical rate constants for two isotopologs of the simplest chemical reaction, $mathrm{H}+{mathrm{H}}_{2}ensuremath{rightarrow}{mathrm{H}}_{2}+mathrm{H}$, are presented. The theoretical results are obtained using accurate quantum dynamics with a converged Born-Oppenheimer potential energy surface and include non-Born-Oppenheimer corrections. The new experiments are carried out using a shock tube and complement earlier investigations over a very large $T$ range, 167 to 2112 K. Experiment and theory now agree perfectly, within experimental error, bringing this 75-year-old scientific problem to completion." @default.
- W2027374034 created "2016-06-24" @default.
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- W2027374034 date "2003-08-07" @default.
- W2027374034 modified "2023-09-23" @default.
- W2027374034 title "<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mi mathvariant=normal>H</mml:mi><mml:mo>+</mml:mo><mml:msub><mml:mi mathvariant=normal>H</mml:mi><mml:mn>2</mml:mn></mml:msub></mml:math>Thermal Reaction: A Convergence of Theory and Experiment" @default.
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- W2027374034 doi "https://doi.org/10.1103/physrevlett.91.063201" @default.
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