FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2027374665> ?p ?o ?g. }

• W2027374665 endingPage "139" @default.
• W2027374665 startingPage "134" @default.
• W2027374665 abstract "The absorption and emission spectra, emission lifetimes, luminescence quantum yields, and electrochemical behavior of the complexes Pd(Phpy)2, Pd(Thpy)2, and Pd(bhq)2 (Phpy−, Thpy−, and bhq−, and bhq− are the deprotonated forms of 2-phenylpyridine, 2-(2-thienyl)pyridine, and benzo[h] quinoline, respectively) have been studied, and the results obtained have been compared with those available for Pt(II) and Pt(IV) complexes containing the same ligands. The intense ligand-centered absorption bands below 340 nm are strongly perturbed by matalation, and the absorption features in the 340–450-nm region are likely to include contributions from formally metal-to-ligand charge-transfer transitions. The structured luminescence spectra observed at 77 K (lifetimes are 0.48, 0.28 and 2.6 ms for Pd(Phpy)2, Pd(Thpy)2, and Pd(bhq)2, respectively) have been assigned to transitions having mainly ligand-centered character, with an increasing metal-to-ligand charge-transfer contribution in going from Pd(bhq)2 to Pd(Phpy)2 and to Pd(Thpy)2. The complexes Pd(phpy)2 and Pd(thpy)2 show two reversible one-electron reduction waves, whereas reduction of Pd(bhq)2 is irreversible, as is the oxidation of the three complexes." @default.
• W2027374665 created "2016-06-24" @default.
• W2027374665 creator A5017090082 @default.
• W2027374665 creator A5054237227 @default.
• W2027374665 creator A5061363270 @default.
• W2027374665 creator A5064530752 @default.
• W2027374665 creator A5075064767 @default.
• W2027374665 date "1988-02-03" @default.
• W2027374665 modified "2023-10-17" @default.
• W2027374665 title "Spectroscopic and Electrochemical Behavior of Cyclometalated Pd(II) Complexes" @default.
• W2027374665 cites W1965613124 @default.
• W2027374665 cites W1971181948 @default.
• W2027374665 cites W2015919589 @default.
• W2027374665 cites W2029870412 @default.
• W2027374665 cites W2032012867 @default.
• W2027374665 cites W2044478684 @default.
• W2027374665 cites W2044974762 @default.
• W2027374665 cites W2045518428 @default.
• W2027374665 cites W2048904134 @default.
• W2027374665 cites W2056072876 @default.
• W2027374665 cites W2060517372 @default.
• W2027374665 cites W2062042307 @default.
• W2027374665 cites W2077136145 @default.
• W2027374665 cites W2090500510 @default.
• W2027374665 cites W2336006772 @default.
• W2027374665 cites W2355627295 @default.
• W2027374665 cites W467418 @default.
• W2027374665 cites W53350837 @default.
• W2027374665 doi "https://doi.org/10.1002/hlca.19880710117" @default.
• W2027374665 hasPublicationYear "1988" @default.
• W2027374665 type Work @default.
• W2027374665 sameAs 2027374665 @default.
• W2027374665 citedByCount "64" @default.
• W2027374665 countsByYear W20273746652012 @default.
• W2027374665 countsByYear W20273746652013 @default.
• W2027374665 countsByYear W20273746652016 @default.
• W2027374665 countsByYear W20273746652017 @default.
• W2027374665 crossrefType "journal-article" @default.
• W2027374665 hasAuthorship W2027374665A5017090082 @default.
• W2027374665 hasAuthorship W2027374665A5054237227 @default.
• W2027374665 hasAuthorship W2027374665A5061363270 @default.
• W2027374665 hasAuthorship W2027374665A5064530752 @default.
• W2027374665 hasAuthorship W2027374665A5075064767 @default.
• W2027374665 hasConcept C116569031 @default.
• W2027374665 hasConcept C118629725 @default.
• W2027374665 hasConcept C119824511 @default.
• W2027374665 hasConcept C121332964 @default.
• W2027374665 hasConcept C125287762 @default.
• W2027374665 hasConcept C145148216 @default.
• W2027374665 hasConcept C147789679 @default.
• W2027374665 hasConcept C148869448 @default.
• W2027374665 hasConcept C155647269 @default.
• W2027374665 hasConcept C170493617 @default.
• W2027374665 hasConcept C17525397 @default.
• W2027374665 hasConcept C178790620 @default.
• W2027374665 hasConcept C179104552 @default.
• W2027374665 hasConcept C185592680 @default.
• W2027374665 hasConcept C24890656 @default.
• W2027374665 hasConcept C2776309666 @default.
• W2027374665 hasConcept C2779485729 @default.
• W2027374665 hasConcept C49040817 @default.
• W2027374665 hasConcept C52859227 @default.
• W2027374665 hasConcept C544153396 @default.
• W2027374665 hasConcept C55493867 @default.
• W2027374665 hasConcept C55904794 @default.
• W2027374665 hasConcept C62520636 @default.
• W2027374665 hasConcept C75473681 @default.
• W2027374665 hasConcept C8010536 @default.
• W2027374665 hasConceptScore W2027374665C116569031 @default.
• W2027374665 hasConceptScore W2027374665C118629725 @default.
• W2027374665 hasConceptScore W2027374665C119824511 @default.
• W2027374665 hasConceptScore W2027374665C121332964 @default.
• W2027374665 hasConceptScore W2027374665C125287762 @default.
• W2027374665 hasConceptScore W2027374665C145148216 @default.
• W2027374665 hasConceptScore W2027374665C147789679 @default.
• W2027374665 hasConceptScore W2027374665C148869448 @default.
• W2027374665 hasConceptScore W2027374665C155647269 @default.
• W2027374665 hasConceptScore W2027374665C170493617 @default.
• W2027374665 hasConceptScore W2027374665C17525397 @default.
• W2027374665 hasConceptScore W2027374665C178790620 @default.
• W2027374665 hasConceptScore W2027374665C179104552 @default.
• W2027374665 hasConceptScore W2027374665C185592680 @default.
• W2027374665 hasConceptScore W2027374665C24890656 @default.
• W2027374665 hasConceptScore W2027374665C2776309666 @default.
• W2027374665 hasConceptScore W2027374665C2779485729 @default.
• W2027374665 hasConceptScore W2027374665C49040817 @default.
• W2027374665 hasConceptScore W2027374665C52859227 @default.
• W2027374665 hasConceptScore W2027374665C544153396 @default.
• W2027374665 hasConceptScore W2027374665C55493867 @default.
• W2027374665 hasConceptScore W2027374665C55904794 @default.
• W2027374665 hasConceptScore W2027374665C62520636 @default.
• W2027374665 hasConceptScore W2027374665C75473681 @default.
• W2027374665 hasConceptScore W2027374665C8010536 @default.
• W2027374665 hasIssue "1" @default.
• W2027374665 hasLocation W20273746651 @default.
• W2027374665 hasOpenAccess W2027374665 @default.
• W2027374665 hasPrimaryLocation W20273746651 @default.
• W2027374665 hasRelatedWork W1994325596 @default.

• next