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- W2027440123 abstract "A desulfurization process, based on the formation and subsequent precipitation of S-alkylsulfonium salts using alkylating agents (CH3I and AgBF4), has been applied to the desulfurization of catalytic-cracked gasoline (CCG). The desulfurization reactivity of each sulfur compound (thiol, disulfide, benzothiophene, tetrahydrothiophene, and thiophenes) in n-decane solution, as a model gasoline, was compared with that obtained from actual CCG. The sulfur compounds in CCG are methylated by the addition of the alkylating agents under moderate conditions and are removed as the precipitates of the corresponding S-alkylsulfonium salts. By employing this new process, the sulfur content of the CCG was decreased from 100 ppm to less than 30 ppm. The benzothiophene in CCG was found to be the most difficult compound to desulfurize, whereas the thiophenes were the most difficult compounds for the model gasoline. Although the olefin concentration was decreased significantly following desulfurization, the resulting CCG dem..." @default.
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- W2027440123 date "2001-01-18" @default.
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- W2027440123 title "A Novel Desulfurization Process for Fuel Oils Based on the Formation and Subsequent Precipitation of S-Alkylsulfonium Salts. 2. Catalytic-Cracked Gasoline" @default.
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- W2027440123 doi "https://doi.org/10.1021/ie000548e" @default.
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