Matches in SemOpenAlex for { <https://semopenalex.org/work/W2027450947> ?p ?o ?g. }
Showing items 1 to 85 of
85
with 100 items per page.
- W2027450947 endingPage "817" @default.
- W2027450947 startingPage "807" @default.
- W2027450947 abstract "Condensation of salicylaldehyde with enantiopure (R)-(1-aryl-ethyl)amines yields the enantiopure Schiff bases (R)-N-(1-aryl-ethyl)salicylaldimine (HSB*; aryl = phenyl, 2-methoxyphenyl, 3- methoxyphenyl, 4-methoxyphenyl (4), 4-bromophenyl (5), 2-naphthyl). These Schiff bases readily react with dinuclear (acetato)(η4-cycloocta-1,5-diene)rhodium(I), [Rh(μ-O 2 CMe)(η 4 -cod)] 2 , to afford the mononuclear complexes, cyclooctadiene-((R)-N-(1-aryl-ethyl)salicylaldiminato-κ 2 N,O)- rhodium(I), [Rh(SB ∗ )(η 4 -cod)] (SB* = deprotonated chiral Schiff base = salicylaldiminate; aryl = phenyl (7), 2-methoxyphenyl, 4-methoxyphenyl, 4-bromophenyl, 2-naphthyl). The complexes have been characterized by IR, UV/vis, 1 H/ 13 C NMR and mass spectrometry, optical rotation as well as by single-crystal X-ray structure determination for 4, 5 and 7. The structure of 5 shows C-Br· · ·π contacts. Compound 7 is only the second example of a Rh(η 4 -cod) complex with a six-membered Rh-N,O-chelate ring" @default.
- W2027450947 created "2016-06-24" @default.
- W2027450947 creator A5000304977 @default.
- W2027450947 creator A5026995371 @default.
- W2027450947 creator A5074012019 @default.
- W2027450947 creator A5090644272 @default.
- W2027450947 date "2007-06-01" @default.
- W2027450947 modified "2023-10-18" @default.
- W2027450947 title "Syntheses, Spectroscopy And Crystal Structures Of (R)-N-(1-Aryl-Ethyl)Salicylaldimines And [Rh{(R)-N-(1-Aryl-Ethyl)Salicylaldiminato}(η<sup>4</sup>-Cod)] Complexes" @default.
- W2027450947 cites W1528130557 @default.
- W2027450947 doi "https://doi.org/10.1515/znb-2007-0609" @default.
- W2027450947 hasPublicationYear "2007" @default.
- W2027450947 type Work @default.
- W2027450947 sameAs 2027450947 @default.
- W2027450947 citedByCount "39" @default.
- W2027450947 countsByYear W20274509472012 @default.
- W2027450947 countsByYear W20274509472013 @default.
- W2027450947 countsByYear W20274509472014 @default.
- W2027450947 countsByYear W20274509472015 @default.
- W2027450947 countsByYear W20274509472016 @default.
- W2027450947 countsByYear W20274509472017 @default.
- W2027450947 countsByYear W20274509472018 @default.
- W2027450947 countsByYear W20274509472020 @default.
- W2027450947 countsByYear W20274509472021 @default.
- W2027450947 countsByYear W20274509472022 @default.
- W2027450947 countsByYear W20274509472023 @default.
- W2027450947 crossrefType "journal-article" @default.
- W2027450947 hasAuthorship W2027450947A5000304977 @default.
- W2027450947 hasAuthorship W2027450947A5026995371 @default.
- W2027450947 hasAuthorship W2027450947A5074012019 @default.
- W2027450947 hasAuthorship W2027450947A5090644272 @default.
- W2027450947 hasBestOaLocation W20274509471 @default.
- W2027450947 hasConcept C115624301 @default.
- W2027450947 hasConcept C118629725 @default.
- W2027450947 hasConcept C145148216 @default.
- W2027450947 hasConcept C146686406 @default.
- W2027450947 hasConcept C155647269 @default.
- W2027450947 hasConcept C161790260 @default.
- W2027450947 hasConcept C178790620 @default.
- W2027450947 hasConcept C185592680 @default.
- W2027450947 hasConcept C2776428424 @default.
- W2027450947 hasConcept C2779256853 @default.
- W2027450947 hasConcept C2780263894 @default.
- W2027450947 hasConcept C2781076698 @default.
- W2027450947 hasConcept C521398313 @default.
- W2027450947 hasConcept C71240020 @default.
- W2027450947 hasConcept C8010536 @default.
- W2027450947 hasConcept C93237805 @default.
- W2027450947 hasConceptScore W2027450947C115624301 @default.
- W2027450947 hasConceptScore W2027450947C118629725 @default.
- W2027450947 hasConceptScore W2027450947C145148216 @default.
- W2027450947 hasConceptScore W2027450947C146686406 @default.
- W2027450947 hasConceptScore W2027450947C155647269 @default.
- W2027450947 hasConceptScore W2027450947C161790260 @default.
- W2027450947 hasConceptScore W2027450947C178790620 @default.
- W2027450947 hasConceptScore W2027450947C185592680 @default.
- W2027450947 hasConceptScore W2027450947C2776428424 @default.
- W2027450947 hasConceptScore W2027450947C2779256853 @default.
- W2027450947 hasConceptScore W2027450947C2780263894 @default.
- W2027450947 hasConceptScore W2027450947C2781076698 @default.
- W2027450947 hasConceptScore W2027450947C521398313 @default.
- W2027450947 hasConceptScore W2027450947C71240020 @default.
- W2027450947 hasConceptScore W2027450947C8010536 @default.
- W2027450947 hasConceptScore W2027450947C93237805 @default.
- W2027450947 hasIssue "6" @default.
- W2027450947 hasLocation W20274509471 @default.
- W2027450947 hasOpenAccess W2027450947 @default.
- W2027450947 hasPrimaryLocation W20274509471 @default.
- W2027450947 hasRelatedWork W1988205009 @default.
- W2027450947 hasRelatedWork W2027450947 @default.
- W2027450947 hasRelatedWork W2080238420 @default.
- W2027450947 hasRelatedWork W2186088815 @default.
- W2027450947 hasRelatedWork W2324898221 @default.
- W2027450947 hasRelatedWork W2362366289 @default.
- W2027450947 hasRelatedWork W2363891833 @default.
- W2027450947 hasRelatedWork W2797189426 @default.
- W2027450947 hasRelatedWork W284033829 @default.
- W2027450947 hasRelatedWork W2950452542 @default.
- W2027450947 hasVolume "62" @default.
- W2027450947 isParatext "false" @default.
- W2027450947 isRetracted "false" @default.
- W2027450947 magId "2027450947" @default.
- W2027450947 workType "article" @default.