FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2027492051> ?p ?o ?g. }

• W2027492051 endingPage "2275" @default.
• W2027492051 startingPage "2270" @default.
• W2027492051 abstract "A novel red-emitting polymer, poly{1,4-phenylenevinylene-(4-dicyanomethylene-4H-pyran)-2,6-vinylene-1,4-phenylenevinylene-2,5-bis(dodecyloxy)-1,4-phenylenevinylene} (PM-PPV), was prepared by the Heck coupling reaction between 2-{2,6-bis[2-(4-bromophenyl)vinyl]pyran-4-ylidene}−malononitrile and 1,4-bis(dodecyloxy)-2,5-divinylbenzene. The EL device based on a single-layer structure (ITO/PM-PPV/Al) showed EL emission with a maximum at 652 nm and an external quantum efficiency of 0.004% at 0.12 mA/mm2, which is higher than that of MEH−PPV (0.0005%, at 0.15 mA/mm2) measured under the same conditions. From the electrochemistry and UV−vis spectroscopy, the HOMO and LUMO energy levels of PM−PPV were figured out to be −5.44 and −3.48 eV, respectively, which are lower than those of MEH−PPV at −4.98 and −2.89 eV, respectively. It is concluded that, by lowering the HOMO and LUMO levels in PM−PPV, the injection rates of the holes and electrons are more balanced than in MEH−PPV. To improve the efficiency, the PPV layer was inserted between anode and PM−PPV layer. The device based on bilayer structure (ITO/PPV/PM−PPV/Al) showed EL emission with a maximum at 646 nm and an external quantum efficiency of 0.05% at 0.18 mA/mm2. The efficiency of the bilayer device was higher than that of the single-layer device by 13 times. The CIE chromaticity coordinates of the bilayer device were x = 0.69 and y = 0.31, which are very close to the CIE chromaticity coordinates (x = 0.67, y = 0.33) of NTSC for the red color." @default.
• W2027492051 created "2016-06-24" @default.
• W2027492051 creator A5032126368 @default.
• W2027492051 creator A5072787561 @default.
• W2027492051 date "2002-04-17" @default.
• W2027492051 modified "2023-10-16" @default.
• W2027492051 title "Synthesis, Electrochemistry, and Electroluminescence of Novel Red-Emitting Poly(<i>p</i>-phenylenevinylene) Derivative with 2-Pyran-4-ylidene−Malononitrile Obtained by the Heck Reaction" @default.
• W2027492051 cites W1965155305 @default.
• W2027492051 cites W1970102351 @default.
• W2027492051 cites W1981754097 @default.
• W2027492051 cites W1981990900 @default.
• W2027492051 cites W1993759905 @default.
• W2027492051 cites W2004671583 @default.
• W2027492051 cites W2007307325 @default.
• W2027492051 cites W2008867477 @default.
• W2027492051 cites W2015671271 @default.
• W2027492051 cites W2028164715 @default.
• W2027492051 cites W2039983786 @default.
• W2027492051 cites W2045557858 @default.
• W2027492051 cites W2054369286 @default.
• W2027492051 cites W2064325362 @default.
• W2027492051 cites W2094309089 @default.
• W2027492051 cites W2099354767 @default.
• W2027492051 cites W2152600777 @default.
• W2027492051 cites W2168832828 @default.
• W2027492051 cites W3023854223 @default.
• W2027492051 doi "https://doi.org/10.1021/cm011553r" @default.
• W2027492051 hasPublicationYear "2002" @default.
• W2027492051 type Work @default.
• W2027492051 sameAs 2027492051 @default.
• W2027492051 citedByCount "86" @default.
• W2027492051 countsByYear W20274920512012 @default.
• W2027492051 countsByYear W20274920512013 @default.
• W2027492051 countsByYear W20274920512014 @default.
• W2027492051 countsByYear W20274920512015 @default.
• W2027492051 countsByYear W20274920512016 @default.
• W2027492051 countsByYear W20274920512017 @default.
• W2027492051 countsByYear W20274920512018 @default.
• W2027492051 countsByYear W20274920512019 @default.
• W2027492051 countsByYear W20274920512020 @default.
• W2027492051 countsByYear W20274920512023 @default.
• W2027492051 crossrefType "journal-article" @default.
• W2027492051 hasAuthorship W2027492051A5032126368 @default.
• W2027492051 hasAuthorship W2027492051A5072787561 @default.
• W2027492051 hasConcept C120665830 @default.
• W2027492051 hasConcept C121332964 @default.
• W2027492051 hasConcept C14158195 @default.
• W2027492051 hasConcept C161790260 @default.
• W2027492051 hasConcept C168896768 @default.
• W2027492051 hasConcept C170029824 @default.
• W2027492051 hasConcept C171250308 @default.
• W2027492051 hasConcept C178790620 @default.
• W2027492051 hasConcept C185592680 @default.
• W2027492051 hasConcept C192157962 @default.
• W2027492051 hasConcept C192562407 @default.
• W2027492051 hasConcept C201780734 @default.
• W2027492051 hasConcept C205507967 @default.
• W2027492051 hasConcept C2777505907 @default.
• W2027492051 hasConcept C2779227376 @default.
• W2027492051 hasConcept C2780513484 @default.
• W2027492051 hasConcept C31625292 @default.
• W2027492051 hasConcept C32909587 @default.
• W2027492051 hasConcept C41625074 @default.
• W2027492051 hasConcept C49040817 @default.
• W2027492051 hasConcept C502130503 @default.
• W2027492051 hasConcept C55493867 @default.
• W2027492051 hasConcept C75473681 @default.
• W2027492051 hasConceptScore W2027492051C120665830 @default.
• W2027492051 hasConceptScore W2027492051C121332964 @default.
• W2027492051 hasConceptScore W2027492051C14158195 @default.
• W2027492051 hasConceptScore W2027492051C161790260 @default.
• W2027492051 hasConceptScore W2027492051C168896768 @default.
• W2027492051 hasConceptScore W2027492051C170029824 @default.
• W2027492051 hasConceptScore W2027492051C171250308 @default.
• W2027492051 hasConceptScore W2027492051C178790620 @default.
• W2027492051 hasConceptScore W2027492051C185592680 @default.
• W2027492051 hasConceptScore W2027492051C192157962 @default.
• W2027492051 hasConceptScore W2027492051C192562407 @default.
• W2027492051 hasConceptScore W2027492051C201780734 @default.
• W2027492051 hasConceptScore W2027492051C205507967 @default.
• W2027492051 hasConceptScore W2027492051C2777505907 @default.
• W2027492051 hasConceptScore W2027492051C2779227376 @default.
• W2027492051 hasConceptScore W2027492051C2780513484 @default.
• W2027492051 hasConceptScore W2027492051C31625292 @default.
• W2027492051 hasConceptScore W2027492051C32909587 @default.
• W2027492051 hasConceptScore W2027492051C41625074 @default.
• W2027492051 hasConceptScore W2027492051C49040817 @default.
• W2027492051 hasConceptScore W2027492051C502130503 @default.
• W2027492051 hasConceptScore W2027492051C55493867 @default.
• W2027492051 hasConceptScore W2027492051C75473681 @default.
• W2027492051 hasIssue "5" @default.
• W2027492051 hasLocation W20274920511 @default.
• W2027492051 hasOpenAccess W2027492051 @default.
• W2027492051 hasPrimaryLocation W20274920511 @default.
• W2027492051 hasRelatedWork W1973563787 @default.
• W2027492051 hasRelatedWork W2004018754 @default.
• W2027492051 hasRelatedWork W2027492051 @default.
• W2027492051 hasRelatedWork W2040142598 @default.

• next