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- W2027601116 abstract "For nonionic surfactants with polyoxyethylene as the sole hydrophilic moiety, Griffin defined the hydrophile-lipophile balance (HLB) value as s of the weight percentage of ethylene oxide in the surfactant molecule. He determined experimentally the HLB value of surfactants required to emulsify a variety of lipids with water. Davies treated the HLB of surfactants as an additive and constitutive property. He assigned numerical values to different functional groups, based on Griffin's experimental HLB values for esters of polyhydric alcohols including sorbitan and polysorbates. Simple calculations show that, for surfactants with polyoxyethylene as the sole hydrophilic moiety, the Davies scale differs substantially from the Griffin scale in the entire range of practical applications. The two scales have different HLB values for the same degree of polyoxyethylation, and the relative size of their HLB units varies widely with increasing degree of polyoxyethylation. Since the Griffin scale has been validated by extensive experiments, the Davies scale is unsuitable for most nonionic surfactants." @default.
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- W2027601116 date "1989-12-01" @default.
- W2027601116 modified "2023-10-16" @default.
- W2027601116 title "Comments on hydrophile-lipophile balance systems" @default.
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- W2027601116 doi "https://doi.org/10.1016/s0021-9797(89)80068-2" @default.
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