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- W2027604930 abstract "The effect of stretching conditions, such as stretching ratios, temperatures and rates of extension, on the relative fraction of β-phase and electron structure as well as dielectric properties of poly(vinylidene fluoride) (PVDF) films was investigated. The fraction of β-phase in PVDF film increases greatly and reaches the peak of 93% after uniaxial stretching. Meanwhile, stretched spherulites and micro-strips paralleling with the stretching direction were observed in the matrix by atomic force microscopy (AFM). The results of fine structure of fluorine and carbon elements in PVDF, identified by X-ray absorption near edge structure (XANES), indicate that the coordination between F and H atoms of the adjacent chains is produced and thus enhances the dielectric response of the stretched film. As a result, the dielectric constant of the stretched film increases by 50% and achieves up to 12.1, as well as the dielectric loss being as low as 0.02." @default.
- W2027604930 created "2016-06-24" @default.
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- W2027604930 date "2013-01-01" @default.
- W2027604930 modified "2023-10-11" @default.
- W2027604930 title "Effect of electroactive phase transformation on electron structure and dielectric properties of uniaxial stretching poly(vinylidene fluoride) films" @default.
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- W2027604930 doi "https://doi.org/10.1039/c3ra43966f" @default.
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