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- W2027626044 abstract "A stereoconvergent access to chiral carbocyclic building blocks is reported. 6-(3′-Hydroxy-4′-methylpent-4′-enyl)-3-methoxy cyclohex-2-enone (1) that consists of four stereoisomers, i.e., racemic ca. 1 : 1 diastereomers, is converted to enantiomerically pure carbocycles through a combination of regioselective catalytic asymmetric reduction and alkylative remote stereoinduction. The present stereoconvergent strategy has allowed the formal synthesis of bioactive (−)-dysidiolide." @default.
- W2027626044 created "2016-06-24" @default.
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- W2027626044 date "2012-01-01" @default.
- W2027626044 modified "2023-09-27" @default.
- W2027626044 title "Stereoconvergent route to chiral cyclohexenone building blocks: formal synthesis of (−)-dysidiolide" @default.
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- W2027626044 doi "https://doi.org/10.1039/c2ob26532j" @default.
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